متوافق مع GHS / OSHA · 16 قسم

ورقة بيانات سلامة المواد

Complete safety information for HR RHINO calcium silicate insulation boards. Prepared in accordance with GHS, OSHA HCS 2012, and EU REACH (Regulation EC 1907/2006).

وثيقة معلومات

This ورقة بيانات سلامة المواد (MSDS/SDS) applies to all calcium silicate insulation board products manufactured by Qingdao Henry Calcium Silicate Board New Materials Co., Ltd. (HR RHINO).

نوع المنتجلوح عزل سيليكات الكالسيوم
رقم CAS1344-95-2
EINECS215-710-8
الصيغة الكيميائيةCaO·SiO₂·xH₂O (Xonotlite)
محتوى الأسبستوسلا يوجد (0%)
تصنيف الحريقA1 غير قابل للاحتراق
تاريخ المراجعةيناير 2025
الإصدار2.0
الصيغةGHS 16 قسم
1
تحديد الهوية

Product Identifier

Product Name: لوح عزل سيليكات الكالسيوم
Trade Name: HR RHINO Calcium Silicate Board
Product Codes: Density grades 220, 250, 270, 300, 400, 500, 800, 850, 980, 1020, 1200 kg/m³

موصى به Use

High-temperature thermal insulation for industrial furnaces, cement kilns, power plant boilers, petrochemical equipment, molten aluminum contact applications, fire protection, and construction insulation.

Manufacturer / Supplier

Qingdao Henry Calcium Silicate Board New Materials Co., Ltd.
Room 407, Building 2, No. 41 Xingcheng Road, Licang District, Qingdao, Shandong Province, China
📧 [email protected]
📱 WhatsApp: +86 156 8913 8837
🌐 www.hrcalciumsilicateboard.com

Emergency Contact

+86 156 8913 8837 (Business hours, UTC+8)

2
Hazards تحديد الهوية

GHS Classification

✓ Not classified as hazardous according to GHS criteria in its finished board form.

Potential Hazards

  • Dust from cutting/machining: مايو cause mechanical irritation to skin, eyes, and respiratory tract
  • Not carcinogenic: Does not contain asbestos or crystalline silica in harmful forms
  • Non-flammable: A1 Fire-Proof classification (EN 13501-1)
  • Not toxic under normal use conditions

Signal Word

None required for intact boards. CAUTION for airborne dust during cutting/machining.

Pictograms

None required for finished product. Dust exposure warnings apply during processing.

3
Composition / معلومات on Ingredients

Calcium silicate boards are manufactured from natural inorganic raw materials with optional reinforcing fibers. The primary component is synthetic xonotlite crystal.

Componentرقم CASConcentration
Xonotlite (6CaO·6SiO₂·H₂O)1344-95-250-80%
Silica (SiO₂, amorphous)7631-86-915-30%
Calcium Oxide (CaO)1305-78-810-25%
Cellulose Fiber / Glass Fiber9004-34-6 / 65997-17-32-8%
Carbon Fiber (N-17 grade only)7440-44-00-3%
✓ Contains NO asbestos, sulfur, chlorine, or other harmful substances.
4
إجراءات الإسعافات الأولية

Eye Contact

Flush eyes immediately with plenty of clean water for at least 15 minutes, lifting upper and lower eyelids. Seek medical attention if irritation persists.

Skin Contact

Wash affected area with soap and water. Remove contaminated clothing. If irritation develops, seek medical advice.

Inhalation (Dust)

Move person to fresh air immediately. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Seek medical attention.

Ingestion

Rinse mouth with water. Do NOT induce vomiting. Give 1-2 glasses of water to dilute. Seek medical attention.

5
إجراءات مكافحة الحريق
✓ غير قابل للاحتراق material (A1 classification, EN 13501-1)

Extinguishing Media

Suitable: Any type — water spray, foam, dry chemical, CO₂ (use to address surrounding fire conditions).
Unsuitable: None.

Specific Hazards

Product does not burn, does not support combustion, and does not emit toxic gases when exposed to high temperatures حتى its service limit.

Protective Equipment

Standard firefighter protective gear and self-contained breathing apparatus (SCBA) recommended for fire in the surrounding area.

6
إجراءات الانطلاق العرضي

Personal Precautions

Avoid generating and breathing dust. Wear appropriate PPE (dust mask, safety glasses, gloves). Ensure adequate ventilation.

Environmental Precautions

Product is inert and non-hazardous to the environment. Prevent large quantities from entering drainage systems, but no specific environmental protection measures required.

Cleanup Methods

  • Pick up solid pieces by hand or use mechanical means
  • Vacuum fine dust with HEPA filter equipment
  • Avoid dry sweeping which generates airborne dust
  • If sweeping is necessary, use dust suppressant or water spray
  • Dispose of collected material according to local regulations
7
التعامل والتخزين

Safe Handling

  • Handle with care to prevent breakage and dust generation
  • Use appropriate lifting equipment for large panels
  • Wear PPE when cutting, drilling, or machining
  • Use local exhaust ventilation during mechanical processing
  • Avoid creating dust clouds

Storage Conditions

  • Location: Dry, covered warehouse
  • Temperature: Ambient (no special requirements)
  • Humidity: Keep dry to prevent moisture absorption
  • Stacking: Store flat on pallets, avoid excessive stack height
  • Protection: Protect from rain, standing water, and mechanical damage
⚠ Note: Although the material absorbs moisture, performance is fully restored after drying. Avoid prolonged wet storage before installation.
8
ضوابط التعرض / الحماية الشخصية

Occupational Exposure Limits

ComponentOSHA PELACGIH TLV
Total Dust (inert)15 mg/m³10 mg/m³
Respirable Dust5 mg/m³3 mg/m³

Engineering Controls

Provide adequate ventilation. Use local exhaust when generating dust during cutting or grinding. Ensure dust collection systems are in good working order.

Personal Protective Equipment (PPE)

  • Respiratory: NIOSH-approved N95 (or equivalent) dust mask during cutting/machining
  • Eye: ANSI-approved safety glasses with side shields
  • Hand: Cotton or leather work gloves
  • Skin: Long-sleeved work clothes; wash skin after contact
  • Feet: Steel-toed safety boots
9
الخواص الفيزيائية والكيميائية
AppearanceRigid white/off-white board
OdorOdorless
pH9–11 (aqueous suspension)
Density220–1200 kg/m³ (depending on grade)
Melting Point>1200°C
Boiling PointNot applicable
Flash PointNot applicable (non-combustible)
FlammabilityA1 غير قابل للاحتراق (EN 13501-1)
Solubility in WaterInsoluble (absorbs moisture)
أقصى درجة تشغيلerature1000°C – 1100°C (depending on grade)
الموصلية الحرارية0.058–0.21 W/m·K (temperature dependent)
10
الاستقرار والتفاعلية

Reactivity

Stable under normal conditions of use and storage.

ثبات كيميائي

Chemically stable. No polymerization or decomposition under recommended conditions.

Conditions to Avoid

  • Direct contact with strong acids (may cause slow decomposition)
  • Temperatures exceeding the rated service temperature
  • Prolonged immersion in water (although performance recovers after drying)

Incompatible Materials

Strong acids (hydrofluoric acid, concentrated sulfuric acid).

Hazardous Decomposition المنتجات

None at temperatures below the rated service limit. Above 1100°C, crystalline transformation may occur but no toxic gases are released.

11
Toxicological معلومات

Routes of Exposure

Inhalation (dust), skin contact, eye contact.

Acute Toxicity

  • Oral LD50: >5000 mg/kg (practically non-toxic)
  • Dermal LD50: >2000 mg/kg (practically non-toxic)
  • Inhalation: Low acute toxicity; dust may cause mechanical irritation

Skin Irritation

Mild mechanical irritation possible from dust contact.

Eye Irritation

Dust may cause mechanical irritation.

Carcinogenicity

✓ NOT listed as carcinogen by IARC, NTP, ACGIH, or OSHA. Product contains no asbestos or hazardous crystalline silica.

Reproductive / Developmental Toxicity

No data available. Not expected to cause reproductive or developmental toxicity based on composition.

12
Ecological معلومات

Ecotoxicity

Inorganic, chemically inert material. No known ecotoxic effects.

Persistence and Degradability

Non-biodegradable. Material is essentially inert in the environment.

Bioaccumulative Potential

Not expected to bioaccumulate.

Mobility in Soil

Immobile; essentially insoluble in water.

Other Adverse Effects

None known. Product is environmentally safe.

13
اعتبارات التخلص

Waste Classification

Not classified as hazardous waste under EPA (RCRA) or EU Waste Framework Directive (2008/98/EC). Can be disposed of as ordinary industrial/construction waste.

Disposal Methods

  • Dispose of in accordance with local, regional, and national regulations
  • Suitable for disposal in approved landfill sites
  • مايو be recycled in construction aggregate applications
  • Packaging: Dispose of per local regulations
14
Transport معلومات
✓ Not classified as dangerous goods for transport.
UN NumberNot regulated
UN Proper Shipping NameNot regulated
Transport Hazard ClassNot applicable
Packing GroupNot applicable
IMDG (Sea)Not regulated
IATA (Air)Not regulated
ADR/RID (Road/Rail)Not regulated
Marine PollutantNo

Transport Precautions

Protect from moisture during transport. Secure cargo to prevent movement and breakage. Standard commercial packaging (wooden pallets with plastic film wrap) is sufficient.

15
Regulatory معلومات

International Regulations

  • GHS (Globally Harmonized System): Not classified as hazardous
  • EU REACH (EC 1907/2006): All components registered / exempt
  • EU CLP Regulation (EC 1272/2008): Not classified
  • USA OSHA HCS 2012 (29 CFR 1910.1200): Not classified as hazardous
  • USA TSCA Inventory: All components listed
  • Canada DSL / WHMIS: Not controlled
  • China GB 30000: Not classified

Product Certifications

  • A1 غير قابل للاحتراق (EN 13501-1)
  • Asbestos-free certificate available
  • Complies with EU Construction المنتجات Regulation (CPR 305/2011) for applicable products
16
Other معلومات

Abbreviations

GHS: Globally Harmonized System · OSHA: Occupational Safety and Health Administration · ACGIH: American Conference of Governmental Industrial Hygienists · TLV: Threshold Limit Value · PEL: Permissible Exposure Limit · PPE: Personal Protective Equipment · REACH: Registration, Evaluation, Authorization and Restriction of Chemicals

References

  • 29 CFR 1910.1200 OSHA Hazard Communication Standard 2012
  • EU Regulation EC 1272/2008 (CLP)
  • EU Regulation EC 1907/2006 (REACH)
  • UN Recommendations on the Transport of Dangerous Goods
  • EN 13501-1 Fire Classification of Construction المنتجات

Disclaimer

The information contained in this Safety Data Sheet is based on our current knowledge and is believed to be accurate as of the revision date. However, no warranty is expressed or implied regarding its accuracy, completeness, or suitability for any particular purpose. The user is responsible for determining the suitability of the product for their specific application and for complying with all applicable laws and regulations. HR RHINO assumes no liability for any injury, damage, or loss resulting from the use of this information or the product described.

— END OF SAFETY DATA SHEET —

تحتاج إلى PDF الرسمي؟

اتصل بنا لاستلام النسخة الرسمية PDF من ورقة السلامة بختم الشركة وتوقيعها للتقديم التنظيمي.

📧 طلب ورقة السلامة PDF واتساب